New easy approach to the synthesis of 2, 5-disubstituted and 2, 4, 5-trisubstituted 1, 3-oxazoles. The reaction of 1-(methylthio) acetone with nitriles

…, P Ramiro, D Molero, J Almy - The Journal of …, 2006 - ACS Publications
The reaction of 1-(methylthio)acetone with different nitriles in the presence of triflic anhydride
led to the one-pot formation of 2-substituted 5-methyl-4-methylthio-1,3-oxazoles in good …

Identification and significance of several sulfur-containing compounds in wine

A Rapp, M Güntert, J Almy - American journal of enology …, 1985 - Am Soc Enol Viticulture
Samples of German wines (Riesling, Scheurebe, Morio-Muskat, Bacchus) were continuously
extracted with Freon 11:dichloromethane; the extracts were concentrated and submitted to …

The reaction of tetralones with nitriles: a simple approach to the synthesis of new substituted benzo [h] quinazolines, benzo [f] quinazolines and dibenzo [a, i] …

…, M Chioua, R Chatt, R Chioua, A Sánchez, J Almy - Tetrahedron, 2006 - Elsevier
The one-pot reaction of 1-tetralone with nitriles in the presence of triflic anhydride affords in
good yields 2,4-disubstituted 5,6-dihydrobenzo[h]quinazolines, which oxidation with DDQ …

Urea analysis for wines

J Almy, CS Ough - Journal of Agricultural and Food Chemistry, 1989 - ACS Publications
An analysis for urea in wine was developed in which urea is isolated by ion exchange and
then derivatized with 1-phenyl-1, 2-propanedione 2-oxime. Measurements of the derivative …

The cysteine reaction with diacetyl under wine‐like conditions: proposed mechanisms for mixed origins of 2‐methylthiazole, 2‐methyl‐3‐thiazoline, 2 …

S Marchand, J Almy, G De Revel - Journal of food science, 2011 - Wiley Online Library
A part of the “bouquet of wines” can be caused by the presence of odorous heterocycles
produced by chemical reactions between S‐amino acids and α‐dicarbonyl compounds. Under …

Electrophilic substitution at saturated carbon. XLIII. Alkylammonium carbanide ion-pair reorganization reactions in base-catalyzed 1, 3-proton transfer in an indene …

J Almy, DJ Cram - Journal of the American Chemical Society, 1969 - ACS Publications
Results Starting Materials and Products. The preparations of (—)-Ih,(—)-Id, and (+)-II-A are
formulated. Acid (—)-III-A of maximum rotation and known configura-tionSab (R) exhibited a …

Electrophilic substitution at saturated carbon. XLIV. Stereochemical and isotopic drowning phenomena

J Almy, DC Garwood, DJ Cram - Journal of the American …, 1970 - ACS Publications
Optically pure (—)-3-/-butyl-1-methylindene-1-h ((—)-Ih), or its counterpart deuterated in the
1 position ((—)-Id), was subjected to simultaneous base-catalyzed racemization, isotopic …

Factors That Control 1, 3-Asymmetric Induction and Intramolecularity in Base-Catalyzed 1, 3-Proton Transfer in an Indene System

J Almy, RT Uyeda, DJ Crum - Journal of the American Chemical …, 1967 - ACS Publications
Equilibrium constants (K) were measured for I<=* II under pure nitrogen. Solutions (0.02 M)
ofl-h and ll-h at 102 ini-butyl alcohol (0.20 Min triethylenediamineor DABCO) gave K= 6.04 …

Favorskii rearrangements. VII. Formation of amides from. alpha.-halo. alpha.'-aryl ketones

FG Bordwell, J Almy - The Journal of Organic Chemistry, 1973 - ACS Publications
Results Reactions with Sodium Methoxide in Methanol.—Reaction of cfs-2-chloro-6-phenylcyclohexanone
(1) with 0.05 M NaOMe in MeOH gave a nearly quan-titative conversion into a …

ART. XVIII.--The Discharge-current from a Surface of large Curvature

JE Almy - American Journal of Science (1880-1910), 1901 - search.proquest.com
THE discharge of electricity from a surface of large curvature has been studied by Warburg,*
and others. Inasmuch as the nature and form of the discharging surface, when a point, or …