The use of cyclic voltammetry for wine analysis: Determination of polyphenols and free sulfur dioxide

O Makhotkina, PA Kilmartin - Analytica Chimica Acta, 2010 - Elsevier
… The first anodic peak at 670 mV corresponds to the oxidation of the OH group on the
benzene ring of ferulic acid, while the second peak at 750 mV corresponds to OCH 3 group …

Uncovering the influence of antioxidants on polyphenol oxidation in wines using an electrochemical method: Cyclic voltammetry

O Makhotkina, PA Kilmartin - Journal of Electroanalytical Chemistry, 2009 - Elsevier
… In fact, the oxidation of ethanol in wine through to acetaldehyde, in the presence of molecular
O 2 , only occurs at a significant rate in the presence of polyphenols and catalytic metals; …

Cocrystal or salt: solid state-controlled iodine shift in crystalline halogen-bonded systems

O Makhotkina, J Lieffrig, O Jeannin… - Crystal Growth & …, 2015 - ACS Publications
… charges derived from isolated molecules [Q(O C═O ) = −1.07; Q(I… In the NIS•Py-NMe 2 crystal
structure, such a O C═O ···I … is less effective for O C═O to attract the I atom [d(O C═O ···I) = …

Catalytic detoxification of 1, 1-dimethylhydrazine aqueous solutions in heterogeneous Fenton system

OA Makhotkina, EV Kuznetsova, SV Preis - Applied Catalysis B …, 2006 - Elsevier
… H 2 O 2 concentration in the solution is impossible due to rapid decomposition of H 2 O 2 on
… Therefore, the determination of the aqueous H 2 O 2 affinity constant K H 2 O 2 was made …

Hydrolysis and formation of volatile esters in New Zealand Sauvignon blanc wine

O Makhotkina, PA Kilmartin - Food chemistry, 2012 - Elsevier
The evolution of the varietal thiol 3-mercaptohexanol acetate (3MHA) and other key aroma
compounds has been monitored in New Zealand Sauvignon blanc wines stored for 1year at …

Water delignification by advanced oxidation processes: Homogeneous and heterogeneous Fenton and H2O2 photo-assisted reactions

OA Makhotkina, SV Preis, EV Parkhomchuk - Applied Catalysis B …, 2008 - Elsevier
… A part of these reacts with H 2 O 2 , when another with lignin:(1) H 2 O 2 ⟶ UV 2 OH (2) H 2
… the compounds, k H 2 O 2 , k OH radical dot , k H O 2 , and k H 2 O 2 , H O 2 were assumed to …

Effect of storage temperature on the chemical composition and sensory profile of Sauvignon Blanc wines

O Makhotkina, B Pineau… - … of Grape and Wine …, 2012 - Wiley Online Library
… The chemical and sensory data were analysed using OriginPro 8 software. To test
significant differences among chemical composition of wines stored for 1 year at four different …

The phenolic composition of Sauvignon blanc juice profiled by cyclic voltammetry

O Makhotkina, PA Kilmartin - Electrochimica Acta, 2012 - Elsevier
O-glucoside and quercetin 3-O-glucuronide. The third peak at 0.9 V had contributions from
the oxidation of non-phenolic compounds. A good correlation was obtained between the total …

Influence of sulfur dioxide additions at harvest on polyphenols, C6-compounds, and varietal thiols in Sauvignon blanc

O Makhotkina, M Herbst-Johnstone… - … Journal of Enology …, 2013 - Am Soc Enol Viticulture
The varietal thiols 3-mercaptohexanol (3MH), derived from odorless precursors in the grape
juice, and 3-mercaptohexyl acetate (3MHA), arising from 3MH during fermentation, are …

Electrochemical oxidation of wine polyphenols in the presence of sulfur dioxide

O Makhotkina, PA Kilmartin - Journal of agricultural and food …, 2013 - ACS Publications
Electrochemical oxidation of three representative wine polyphenols (catechin, caffeic acid,
and quercetin) in the presence of sulfur dioxide in a model wine solution (pH = 3.3) was …