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Free, Bound, and Total Sulfur Dioxide (SO2) during Oxidation of Wines

Gavin L. Sacks, Patricia A. Howe, Matthew Standing, John C. Danilewicz
Am J Enol Vitic. April 2020 : ajev.2020.19083; published ahead of print April 29, 2020 ; DOI: 10.5344/ajev.2020.19083
Gavin L. Sacks
1Professor, Cornell University, Department of Food Science, Ithaca, NY 14853
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  • For correspondence: gls9@cornell.edu
Patricia A. Howe
2University of California, Davis, Department of Viticulture and Enology, Davis, CA 95616
5Previous address: Constellation Brands, 166 Gateway Road East, Napa, CA 94559
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Matthew Standing
3Plumpton College, University of Brighton, Ditchling Road, Plumpton, Nr Lewes, East Sussex BN7 3AE. UK
6Current address: Dehlinger Winery, 4101 Vine Hill Road, Sebastopol, CA, 95472
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John C. Danilewicz
4Private Laboratory: 44 Sandwich Road, Ash, Canterbury, Kent CT3 2AF, United Kingdom
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Data supplements

  • Supplemental Table 1  Free, bound, and total SO2 in wines during storage experiments.

    Supplemental Figure 1  Total and free SO2 versus storage time for packaging material, temperature, and wine combinations not shown in Figure 2.

    Supplemental Figure 2  Total versus free SO2 plots replotted from data in earlier publications. (Top left) Three red wines stored under air-saturated conditions (~8.5 mg/L O2) from data published in Danilewicz and Standing (2018); (Top right) two white wines stored following an initial saturation (~7.5 mg/L O2) from data published in Danilewicz (2016); (Bottom) white wines following SO2 additions from data published in Burroughs and Sparks (1973b).

    Supplemental Figure 3   Re-analyzed data for two wines (Müller-Thurgau, left column; and Madeleine-Sylvaner, right column) from free and bound SO2 data in Table 2 of Burroughs and Sparks (1973b). Plotted bound SO2 values for Müller-Thurgau were 16 mg/L less than what was in the original table to correct for the discrepancy between predicted and measured values, as reported by the earlier work. Apparent dissociation constant (Kd ) plots were prepared as described for Figure 5 in the main manuscript.



    Files in this Data Supplement:

    • Supplemental_Data-figures.pdf
    • Supplemental_Data-table.pdf
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Free, Bound, and Total Sulfur Dioxide (SO2) during Oxidation of Wines
Gavin L. Sacks, Patricia A. Howe, Matthew Standing, John C. Danilewicz
Am J Enol Vitic.  April 2020  ajev.2020.19083;  published ahead of print April 29, 2020 ; DOI: 10.5344/ajev.2020.19083

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Free, Bound, and Total Sulfur Dioxide (SO2) during Oxidation of Wines
Gavin L. Sacks, Patricia A. Howe, Matthew Standing, John C. Danilewicz
Am J Enol Vitic.  April 2020  ajev.2020.19083;  published ahead of print April 29, 2020 ; DOI: 10.5344/ajev.2020.19083
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